Savante,
As a general rule you only get the "spare pair" to play with.
The 24v for the manipulator is switched in the ROV (from 48v), so there is no way to disconnect it at the surface. You could play with that voltage, but i think what your asking is can you use the 48v cables coming out of the sub to the manipulator as another data line, and the answer is no.
There are other options though. You could run a separate cable mated to the tether to your gear and get your data. I’ve seen that doen quite a few times, especially when you have a damaged tether. Hope this helps!
Chief